Intramolecular Pancake Bonding in Helical Structures
نویسندگان
چکیده
منابع مشابه
Intramolecular Pancake Bonding in Helical Structures.
We show that diradicaloid helical conjugated molecules can display strong through-space bonding interactions. These interactions are analogous to π-stacking pancake bonding widely observed for dimers and other aggregates of stable π-conjugated radicals. We show that these multicenter interactions can have a significant stabilizing effect, but they depend in subtle ways on the specific overlap a...
متن کاملConventional and Unconventional Intramolecular Hydrogen Bonding in some Beta-diketones
This study presents our view of unconventional and conventional intramolecular hydrogen bonds (HBs) for some beta-diketones theoretically and experimentally. According to our results, the groups such as Phenyl and t-But in beta positions increase and CF3 group decrease IHB strength, respectively. For better understanding of the substitution effects, the compounds with similar and different subs...
متن کاملSpecial issue: intramolecular hydrogen bonding.
Intramolecular hydrogen bonds play critical structure- and function-serving roles in biological and synthetic molecular systems. This special issue, through eight contributions, showcases the prominence of these non-covalent interactions within several scientific disciplines, and in various structural contexts and environments. Reported, for example, are the consequences of intramolecular hydro...
متن کاملIntramolecular hydrogen bonding in flavin adenine dinucleotide.
Data obtained by means of proton magnetic resonance spectroscopy indicate that specific association of FMN occurs with AMP in aqueous solution, because much weaker interaction is observed with FMN of either GMP or CMP. A comparison of FAD with a 1:1 mixture of FMN and AMP suggests that the flavin is involved in an intramolecular hydrogen bonding with the adenine moiety of FAD. The temperature d...
متن کاملPersistent Currents in Helical Structures
Recent discovery of mesoscopic electronic structures, in particular the carbon nanotubes, made necessary an investigation of what effect may helical symmetry of the conductor (metal or semiconductor) have on the persistent current oscillations. We investigate persistent currents in helical structures which are non-decaying in time, not requiring a voltage bias, dissipationless stationary flow o...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Chemistry – A European Journal
سال: 2017
ISSN: 0947-6539,1521-3765
DOI: 10.1002/chem.201700999